Publications
Facile Generation of Active Sites in Nodes of Ni-MFU-4l Metal-Organic Framework for Hydrogenation Reaction
M. A. Khoshooei, J. Hofmann, H. Xie, S. M. Vornholt, Y. Yoo, F. Sha, Y. Chen, K. O. Kirlikovali, K. W. Chapman, and O. K. Farha
ACS Materials Lett. 2026, 8, 1, 213–219. DOI: 10.1021/acsmaterialslett.5c01329

Spin Glass Behavior and Giant Magnetoresistance via Aliovalent Fe/Ni Alloying in Amorphous Tetrathiafulvalene-Tetrathiolate Coordination Polymers
C.-Y. Lien, J.-H. Chen, A. O. Schouten, G. R. Wilkinson, D. Wang, J. Hofmann, M. E. Czaikowski, B. Lavina, A. S. Filatov, K. W. Chapman, A. P. Higginbotham, D. V. Talapin, D. A. Mazziotti, H. S. La Pierre, S. N. Patel, and J. S. Anderson
J. Am. Chem. Soc. 2025, 147, 43, 39590–39598. DOI: 10.1021/jacs.5c12985

Pre-synthetic redox control of structure and properties in copper TTFtt coordination polymers
N. Jiang, S. Velliyarat, C.-Y. Lien, H. L. Nguyen, J. Hofmann, J.-H. Chen, A. Ramanathan, A. S. Filatov, H. S. La Pierre, S. Patel, K. W. Chapman, J.-Niklas Boyn, and J. S. Anderson
Chem. Sci. 2025, 16, 19304. DOI: 10.1039/d5sc03070f

Benchmarking a modern laboratory-based powder diffraction instrument for in situ studies in transmission geometry
S. M. Vornholt, J. J. Ferrari, B. A. Sanchez Monserrate, B. G. Mullens, J. Hofmann, M. L. Beauvais, P. J. Chupas, and K. W. Chapman
J. Appl. Crystallogr. 2025, 58, 5, 1852-1858. DOI: 10.1107/S1600576725006259

Introducing metal–sulfur active sites in metal–organic frameworks via post-synthetic modification for hydrogenation catalysis
H. Xie, M. A. Khoshooei, M. Mandal, S. M. Vornholt, J. Hofmann, L. M. Tufaro, K. O. Kirlikovali, D. A. Grimes, S. Lee, S. Su, S. Reischauer, D. Sengupta, K. Fahy, K. Ma, X. Wang, F. Sha, W. Gong, Y. Che, J. G. Vitillo, J. S. Anderson, J. M. Notestein, K. W. Chapman, L. Gagliardi, and O. K. Farha
Nat. Chem. 2025, 17, 1514–1523. DOI: 10.1038/s41557-025-01876-y

A Disordered Rock Salt Anode for Long-Lived All-Vanadium Sodium-Ion Battery
H. Lin, Z. Wang, O. Solares, S. Huber, J. Hofmann, S. Danitz, W.-T. Peng, K. Zhou, P.-C. Lee, H. Liu, Z. Hui, R. Liu, M. Liu, W. Tang, J. Wu, Z. Chen, K. W. Chapman, S. P. Ong, and P. Liu
Adv. Mater. 2025, 37, 46, 2503143. DOI: 10.1002/adma.202503143

Suppressing Phase Transitions and High-Pressure Amorphization through Tethered Organic Cations in Organochalcogenide-Halide Perovskites
J. Li, J. Hofmann, R. M. Stolz, J. Wen, C. R. Deschene, H. Bartels, Z. Liu, A. Salleo, Y. Lin, K. W. Chapman, and H. I. Karunadasa
J. Am. Chem. Soc. 2025, 147, 22, 19026–19038. DOI: 10.1021/jacs.5c03696

Structure and Synthesizability of Iron–Sulfur Metal–Organic Frameworks
J. Mao, N. Jiang, A. Daru, A. S. Filatov, J. Hofmann, S. M. Vornholt, K. W. Chapman, J. S. Anderson, and A. L. Ferguson
J. Am. Chem. Soc. 2025, 147, 21, 17651–17667. DOI: 10.1021/jacs.4c16341

Increasing the Energy Density of Disordered Rock Salt Anodes for Fast-Charging Lithium-Ion Batteries
H. Lin, W.-T. Peng, Z. Wang, J. Hofmann, S. M. Vornholt, H. Liu, S. Wang, J. Holoubek, K. Zhou, Q. Miao, S. Huber, K. W. Chapman, S. P. Ong, and P. Liu
ACS Materials Lett. 2025, 7, 2, 699–706. DOI: 10.1021/acsmaterialslett.4c02086

3D Lead-Organoselenide-Halide Perovskites and their Mixed-Chalcogenide and Mixed-Halide Alloys
H. Karunadasa, J. Li, Y. Wang, S. Saha, Z. Chen, J. Hofmann, J. Misleh, K. W. Chapman, J. A. Reimer, and M. R. Filip
Angew. Chem. Int. Ed. 2024, 63, e202408443. DOI: 10.1002/anie.202408443

Node Distortions in UiO-66 Inform Negative Thermal Expansion Mechanisms: Kinetic Effects, Frustration, and Lattice Hysteresis
S. M. Vornholt, Z. Chen, J. Hofmann, and K. W. Chapman
J. Am. Chem. Soc. 2024, 146, 25, 16977–16981, DOI: 10.1021/jacs.4c05313.

Probing Structural Transformations and Degradation Mechanisms by Direct Observation in SIFSIX-3-Ni for Direct Air Capture
M. L. Barsoum#, J. Hofmann#, H. Xie, Z. Chen, S. M. Vornholt, R. dos Reis, N. Burns, S. Kycia, K. W. Chapman, V. P. Dravid, and O. K. Farha
J. Am. Chem. Soc. 2024, 146, 10, 6557–6565, DOI: 10.1021/jacs.3c11503.
